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From Russia With Love (1963)

Director: Terence Young
Cast: Sean Connery, Daniela Bianchi and Robert Shaw

The second James Bond film is considered by many to be the best in the 007 series. Sent to Istanbul to secure a top-secret Russian decoding machine, Bond falls for a Russian agent, nearly meets death by a poisonous switchblade (protruding from the shoes of a female assassin) and dukes it out with the deadly killer played by Shaw.