electrolysis

Commercial Applications of Electrolysis

Various substances are prepared commercially by electrolysis, e.g., chlorine by the electrolysis of a solution of common salt; hydrogen by the electrolysis of water; heavy water (deuterium oxide) for use in nuclear reactors, also by electrolysis of water. A metal such as aluminum is refined by electrolysis. A solution of aluminum oxide in a molten mineral decomposes into pure aluminum at the cathode and into oxygen at the anode. In these examples the electrodes are inert.

In electroplating, the plating metal is generally the anode, and the object to be plated is the cathode. A solution of a salt of the plating metal is the electrolyte. The plating metal is deposited on the cathode, and the anode replenishes the supply of positive ions, thus gradually being dissolved. Electrotype printing plates, silverware, and chrome automobile trim are plated by electrolysis.

The English scientist Michael Faraday discovered that the amount of a material deposited on an electrode is proportional to the amount of electricity used. The ratio of the amount of material deposited in grams to the amount of electricity used is the electrochemical equivalent of the material. Actual electric consumption may be as high as four times the theoretical consumption because of such factors as heat loss and undesirable side reactions.

The Columbia Electronic Encyclopedia, 6th ed. Copyright © 2012, Columbia University Press. All rights reserved.